Metalworking fluids (MWF) do far more than cool and lubricate. Without the right corrosion-inhibitor (CI) package, machined parts, fixtures, and even machine tools can rust or stain within hours—ruining finish quality, driving rework, and shortening equipment life. Corrosion inhibitors slow the electrochemical reactions that attack metal surfaces by forming protective films, neutralizing corrosive species, or passivating the metal.1

Why corrosion inhibitors are necessary
Metal removal and forming operations constantly create fresh, reactive metal surfaces, entrain oxygen, and atomize water—perfect conditions for flash rusting on ferrous alloys and staining on aluminum, copper, and brass. Tramp oils, hard-water salts, and residual chlorides can accelerate the problem. Well-selected CIs protect parts between operations, preserve dimensional accuracy, and keep machines looking and running like new—ultimately lowering total cost per part.1

Where they matter in metalworking
Corrosion control is important across nearly every MWF use case:

  • Water-miscible coolants for cutting & grinding: High surface area, aeration, and water exposure make these especially prone to flash rust and staining; CI selection and concentration control are critical. Standard lab tests (see below) are often specified in coolant approvals.2
  • Forming & stamping (emulsions and synthetics): Mixed-metal lines need CIs that protect ferrous substrates without staining aluminum or yellow metals.3
  • Straight oils & temporary preservatives: Oils often rely on “film-forming” and polar rust preventives to deliver longer interval protection or storage stability.4

Request More Information

The main families of corrosion inhibitors (and when to use them)
The best CI systems blend chemistries to cover multiple metals, waters, and duty cycles. Below is a practical map of what’s commonly used.5

  1. Neutralizing/alkaline reserves (amines, borates, silicates). Maintain a mildly alkaline pH to slow ferrous corrosion and buffer acidic contaminants. Alkanolamines (e.g., MEA/DEA/TEA) and borates are ubiquitous in water-based MWF; they also improve soap formation and lubricity. Watch for regulatory and labeling constraints depending on region and formulation class.
  2. Film-formers & polar adsorbers (carboxylates, fatty acid–amine salts, succinates). Adsorb to steel and cast-iron surfaces, displacing water and creating hydrophobic barriers; widely used in both emulsions and oils. Often “ashless,” they’re friendly to downstream heat-treat and coating.
  3. Phosphorus-based inhibitors (phosphate esters, complex esters). Provide broad-spectrum protection (ferrous and non-ferrous) and can double as boundary lubricants/EP boosters—useful in mixed-metal shops and hard-water. Careful selection avoids yellow-metal staining.6
  4. Yellow-metal protectors (benzotriazole, tolyltriazole; thiadiazoles for Cu alloys). Excellent on copper and brass; commonly paired with ferrous inhibitors in multi-metal fluids. Note that triazoles are under ongoing environmental and occupational review in some regions—work with the Barentz team on responsible use and potential alternatives.
  5. Inorganic/oxygen-scavenging & passivating salts (molybdate, metasilicate, borate). Used selectively in synthetics and cleaners; strengthen passive films and reduce cathodic activity. Compatibility and water quality matter.
  6. Oil-phase rust preventives (for straight oils & RP fluids). Packages combine polar corrosion preventives with waxy/oleaginous carriers for storage and shipment protection; chosen for desired film type (dry-to-touch, oily, de-waterers).

How performance is measured (the tests your customers ask about)

  • ASTM D4627 (Iron Chip Corrosion, water-miscible fluids): Cast-iron chips and dilution “breakpoint” establish CI robustness across concentrations—great for coolant development and QC.
  • DIN 51360-2 (Grey iron chip/filter-paper test): Common in Europe for water-dilutable fluids; similar purpose to D4627.
  • ASTM D1748 (Humidity Cabinet): Evaluates rust prevention of oils/preservatives on steel panels under high humidity—useful for straight oils and temporary RPs.

Practical selection tips

  • Match metallurgy. Pair ferrous inhibitors with yellow-metal protectors when shops cut both steels and copper-containing alloys; screen for aluminum stain with the specific alloys you’ll see.
  • Design for your water. Hardness and anions (chloride, sulfate) can hinder CI performance; test at customer-realistic dilutions and water chemistries.
  • Mind the whole system. CIs must coexist with EP/antiwear, biocides, defoamers, and surfactants; some chemistries (e.g., highly reactive sulfur) can stain non-ferrous metals. The Barentz team can help you choose the best components for your formulation.
  • Watch the regs. Triazoles and certain amines face evolving regulatory scrutiny; consult the Barentz Technical Team for current substance lists and plan alternatives where needed.

How Barentz supports metalworking-fluid manufacturers
Barentz partners with MWF blenders to build fit-for-purpose CI packages and validate them quickly:

  • Application-driven selection. We help you create the best final formulations by incorporating high-quality components to cover your exact needs—minimizing stain risk while preserving tool life.
  • Multi-metal & regulatory road-mapping. If your portfolio sells into regions with heightened scrutiny (e.g., for benzotriazole/tolyltriazole), we’ll propose routes that maintain yellow-metal protection while supporting compliance strategies noted in current substance lists.
  • Broader additive integration. Because inhibitors interact with base stocks, EP packages, defoamers, and biocides, our team helps you land on balanced, low-foam, stable formulations that still hit corrosion targets—cutting time from lab to line. Insights reflect industry best practices.

References

  1. AMPP. (n.d.). What is corrosion? https://ampp.org/technical-research/what-is-corrosion
  2. STLE. (2016, April). Minding the MetalworkingFluids. https://www.stle.org/images/pdf/STLE_ORG/BOK/LS/Lubricant_Manufacturing/Minding%20the%20Metalworking%20Fluids_April16%20tlt.pdf
  3. STLE. (2020, March). Feature. https://www.stle.org/files/TLTArchives/2020/03_March/Feature.aspx
  4. STLE. (2015, August). Metal Corrosion Preventatives: Protect Metal and Specific Applications. https://www.stle.org/images/pdf/STLE_ORG/BOK/LS/Additives/Metal%20Corrosion%20Preventatives_Protect%20Metal%20and%20Specific%20App_Aug15%20TLT.pdf
  5. Tang, Z. (n.d.). [PDF file]. NTIC (Shanghai) Co., Ltd., Shanghai 201702, China. https://e-tarjome.com/storage/panel/fileuploads/2019-08-28/1566990895_E13170-e-tarjome.pdf
  6. STLE. (2022, March). Feature. https://www.stle.org/files/TLTArchives/2022/03_March/Feature.aspx

View our corrosion inhibitor portfolio

Click Here

Sign-up to Stay in the Know

Sign-up for out newsletter to stay on top of market trends, new product innovation and more! And as always, make sure you’re following us on Linkedin!

Subscribe to our newsletter today